Lead-zinc (Pb-Zn) smelting is one of the largest anthropogenic emission sources of mercury (Hg) in China and the world. In the last few decades, Hg emission control devices have been employed in Pb-Zn smelters to reduce Hg emissions. To evaluate the effectiveness of Hg emission control, this study uses Hg isotopes to trace the sources of Hg in soils and reservoir sediments near the Zhuzhou smelter, the largest Zn production facility in China. The results showed that Hg concentrations in reservoir sediments were higher than those in soils at the three study sites, suggesting that reservoir sediments accumulate more Hg than soils do under the same con-ditions. Hg concentrations and deposition fluxes in reservoir sediments have dramatically decreased since the year 2000, suggesting the effectiveness of Hg emission control in the Zhuzhou smelter. Mercury isotope com-positions in soil suggest binary mixing of Hg from the Zhuzhou smelter and the local background, and the contribution of Hg from the Zhuzhou smelter to soils and sediment is mainly a function of location and distance from the source. The model output suggested that approximately 61-75% of Hg in reservoir sediments was sourced from the Zhuzhou smelter. This study demonstrates that legacy Hg will continue to be a source to local ecosystems, even after Hg emission control has been implemented for decades.

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