The high-temperature unit-cell parameters and volumes of three Li-bearing tourmalines (elbaite (CC05), elbaite (CC11) and schorl (D54)) have been determined through in situ synchrotron radiation angle-dispersive X-ray diffraction experiments. No phase transition of these tourmalines has been observed up to the maximum temperature in this study. The volumetric thermal expansion coefficients of the three Li-bearing tourmalines are determined from the measured unit-cell volumes at high temperatures with Berman's equations. And the elbaite (CC05) has the least volumetric thermal expansion coefficients among the three Li-bearing tourmalines in this study. Furthermore, the axial thermal expansion behavior of these Li-bearing tourmalines is also fitted with "linearized" Berman's equation. The results show that Li-bearing tourmalines has an intense anisotropic axial thermal expansivity, where the c-axis has a larger axial thermal expansion coefficient than a-axis. The potential factors influencing on the thermal expansivity and the anisotropic axial thermal expansivities of Li-bearing tourmalines are further discussed.