The vibrational, electrical and structural properties of gallium sulfide (Ga2S3) were explored by Raman spectroscopy, electrical conductivity measurements, high-resolution transmission electron microscopy and first-principles theoretical calculations under different pressure environments up to 36.4 GPa. Upon compression, Ga2S3 underwent a first-order structural phase transition accompanied by a semiconductor-to-metal transformation at 17.2 GPa under non-hydrostatic conditions, whereas, the transition occurred at a much lower pressure of 11.3 GPa under hydrostatic conditions because of the influence of the pressure medium. Upon decompression, two possible new high-pressure polymorphs were observed at 8.0 and 3.0 GPa under non-hydrostatic conditions, and similar transition points were obtained under hydrostatic conditions. The structural and electrical transport evolution for Ga2S3 upon compression and decompression can help us to deeply understand the high-pressure behaviors of other similar A(2)B(3)-type structural compounds.
| Publication name | JOURNAL OF MATERIALS CHEMISTRY C Volume9 Issue8 Page2912-2918 DOI10.1039/d0tc06004f PublishedFEB 28 2021 | | Author(s) | Yang, Linfei; Jiang, Jianjun; Dai, Lidong; Hu, Haiying; Hong, Meiling; Zhang, Xinyu; Li, Heping; Liu, Pengfei | | Corresponding author(s) | DAI Lidong; HU Haiying
dailidong@vip.gyig.ac.cn; huhaiying@mail.gyig.ac.cn
Linyi Univ, Coll Resources & Environm Sci, Shandong Prov Key Lab Water & Soil Conservat & En, Linyi 276000, Shandong, Peoples R China | | Author(s) from IGCAS | YANG Linfei; HONG Meiling; ZHANG Xinyu; LI Heping | View here for the details
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