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Thermal expansion of ellinaite (beta-CaCr2O4): an in-situ high temperature X-ray diffraction study TEXT SIZE: A A A
The thermal expansion of orthorhombic CaFe2O4-type beta-CaCr2O4, ellinaite, was studied by high temperature in-situ synchrotron X-ray diffraction measurements in the temperature range of 301-973 K at atmospheric pressure. Based on the obtained data, the thermal expansion coefficients of beta-CaCr2O4 were determined as 2.84(3) x 10(-5) K-1, 1.08(1) x 10(-5) K-1, 0.79(1) x 10(-5) K-1, 0.99(1) x 10(-5) K-1 for volume, a-, b- and c axis, respectively. An anisotropic behavior was observed because the axial expansivity for the b axis is smaller than those of the a- and c axis. Combined with available experimental results, the isobaric heat capacity (C-p) of beta-CaCr2O4 was evaluated by using a Kieffer's model with Raman spectroscopy data and compared with previous studies. The isochoric heat capacity (C-v), standard entropy (S-298(0)) and Debye temperature (theta(D)) of beta-CaCr2O4 were also determined.
 

Publication name

 PHYSICS AND CHEMISTRY OF MINERALS Volume: 48 Issue: 1 Article Number: 2 DOI: 10.1007/s00269-020-01126-2 Published: JAN 2 2021

Author(s)

 Xue, Weihong; Zhai, Kuan; Zhai, Shuangmeng

Corresponding author(s) 

 XUE Weihong 
 xueweihong@mail.gyig.ac.cn
 Chinese Acad Sci, Key Lab High Temp & High Pressure Study Earths In, Inst Geochem, Guiyang 550081, Peoples R China.

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