Multiple types of persistent organic pollutants (POPs), such as polychlorinated biphenyls (PCBs), polychlorinated naphthalenes (PCNs), and hexachlorobenzene (HCB), can be unintentionally released from combustion or thermal industrial processes, which are speculated to be the main sources of these contaminants, as they were banned on production and use since several decades ago. In this study, concentrations and sources of 40 PCBs, 39 PCNs, and HCB were analyzed in air samples collected during the period 2012-2015 at a background site in east China. Sigma PCBs, Sigma PCNs, and HCB were in the range of 9 -341 pg/m(3), 6-143 pg/m(3), and 14-522 pg/m(3), respectively. Seasonal characteristics with high levels in winter and low levels in summer were observed for PCNs and HCB. PCBs also exhibited slightly higher levels in winter. Source apportionment was conducted, using polycyclic aromatic hydrocarbons (PAHs) as combustion sources indicator, combined with principal component analysis (PCA) and positive matrix factorization (PMF) model. The results indicated that the legacy of past produced and used commercial PCBs was the dominant contributor (similar to 56%) to the selected PCBs in the atmosphere in east China. PCNs were mainly emitted from combustion sources (similar to 64%), whereas HCB almost entirely originated from combustion process (>90%). (C) 2020 Elsevier Ltd. All rights reserved.