Home | Contact Us | Sitemap | 中文 | CAS | Director's Email
 
Location:Home > Papers > Recent Papers
Theoretical studies on the hydrous lower mantle and D''layer minerals TEXT SIZE: A A A
The incorporation mechanisms and elastic properties of hydrous Bridgmanite (Brg) and post-Perovskite (PPv) are investigated by using first principles calculations at the lower mantle pressures. The elastic properties calculations in both (Al, Fe)-free and (Al, Fe)-bearing systems give evidences that hydrogen has less effect on the elastic wave velocities and moduli in (Al, Fe)-free and Al-bearing system. However, the elastic wave velocities and moduli, especially the shear velocity V-S and the shear modulus G, are remarkably sensitive to the presence of hydrogen in the Fe-bearing system. The calculated shear velocity anomaly (dV(S)) are -2.9% for FeSi3+H-Brg and -3.1% for FeSi3+H-PPv, which are very close to the average anomaly value of LLSVPs. This result may imply the Ferric-bearing hydrous MgSiO3 is likely a dominated mineral in LLSVPs. Density functional perturbation theory (DFPT) and QHA calculation have also been performed to determine the P-T phase diagram for different hydrous systems. The phase transition boundary between Brg and PPv shifts to higher or lower pressures when the hydrogen atom substitutes in the Mg or Si sites in the lattice, respectively. The existence of volatiles such as hydrogen may account for the strong lateral chemical heterogeneity in lowermost mantle. (C) 2019 Elsevier B.V. All rights reserved.
 

Publication name

 EARTH AND PLANETARY SCIENCE LETTERS, 525 10.1016/j.epsl.2019.115753 NOV 1 2019

Author(s)

 Jiang, Jiajun; Zhang, Feiwu

Corresponding author(s) 

 ZHANG Feiwu 
 zhangfeiwu@vip.gyig.ac.cn  
 Chinese Acad Sci, Inst Geochem, State Key Lab Ore Deposit Geochem, Guiyang 550081, Guizhou, Peoples R China. 

View here for the details 

Copyright © Institute Of Geochemistry, Chinese Academy of Sciences All Rights Reserved.
Address: 99 West Lincheng Road, Guanshanhu District, Guiyang, Guizhou Province 550081, P.R.China
Tel: +86-851-85895239 Fax: +86-851-85895239 Email: web_en@mail.gyig.ac.cn