Single crystal growth, crystalline structure investigation and high-pressure behavior of impurity-free siderite (FeCO3) |
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Single crystals of impurity-free siderite were grown successfully using high-temperature-pressure annealing. The size of crystals ranged up to 100 mu m, and they exhibited a rhomboid shape upon cleavage along the (101) plane. The composition of Fe0.9988 +/- 0.0011CO3 was quantified using electron probe analysis. Accurate crystalline structural data were investigated by means of single crystal X-ray diffraction (XRD) and the unit cell dimensions obtained in the rhombohedral symmetry of the R (3) over barc space group were a = 4.6861(3) and c = 15.362(2), and the final R = 0.0499. Using in situ synchrotron XRD, the high-pressure behavior of impurity-free siderite was investigated up to 20 GPa at ambient temperature. The pressure-volume (P-V) EoS was fitted by a third-order Birch-Murnaghan equation, and the isothermal bulk modulus was K-0 = 97.5(11) GPa for K-0' = 4. High-pressure Raman spectroscopy was performed at up to 30 GPa at ambient temperature, and the Raman bands shifted as the increase of pressure (d nu(i)/dP) was determined. In combination with the high-pressure Raman results and the bulk modulus K-0, the mode Gruneisen parameters of each vibration were calculated. Meanwhile, high-temperature Raman spectroscopy was carried out at up to 300 degrees C and the Raman band shift (d nu(i)/dt) was also quantified. Publication name | PHYSICS AND CHEMISTRY OF MINERALS, 45 (9):831-842; 10.1007/s00269-018-0965-y OCT 2018 | Author(s) | Liang, Wen; Yin, Yuan; Li, Zeming; Li, Rui; Li, Lin; He, Yu; Dong, Haini; Li, Zengsheng; Yan, Shuai; Zhai, Shuangmeng; Li, Heping | Corresponding author(s) | LI Heping liheping@vip.gyig.ac.cn Chinese Acad Sci, Inst Geochem, Key Lab High Temp & High Pressure Study Earths In, Guiyang 550081, Guizhou, Peoples R China. | View here for the details
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