Home | Contact Us | Sitemap | 中文 | CAS | Director's Email
 
Location:Home > Papers > Recent Papers
Pressure Impact on the Crystal Structure, Optical, and Transport Properties in Layered Oxychalcogenides BiCuChO (Ch = S, Se) TEXT SIZE: A A A
The layered oxychalcogenides BiCuChO (Ch = S, Se, Te) represent a unique family of two-dimensional semiconductors with extraordinary optoelectronic and thermoelectric properties. Chemical strategies such as elemental doping have been used to modify their crystal structures and electronic configurations for better photocatalytic performances. Herein, we report the pressure impact on the crystalline and electronic band structures of BiCuChO (Ch = S, Se) with in situ synchrotron X-ray diffraction, Raman spectroscopy, electric resistivity and photocurrent measurements, and first principle calculations. Under pressure, the crystalline lattices shrink continuously without symmetry breaking, which enhances the crystal field splitting; on the other hand, the pressure-induced charge delocalization causes the band broadening. The competition between the crystal field and charge delocalization demonstrates an efficient tool for band gap engineering: the electrical conductivity is enhanced below 12 GPa and monotonically decreases up to 40 GPa. In addition, BiCuSeO exhibits considerable photocurrent up to 40 GPa, which suggests its potential application in pressure-responsive optoelectrical devices. The comprehensive studies of the pressure effect on the crystal structure and electronic properties in two-dimensional semiconductors provide and in-depth understanding for developing new optoelectronic materials under extreme conditions.
 

Publication name

 JOURNAL OF PHYSICAL CHEMISTRY C, 122 (28):15929-15936; 10.1021/acs.jpcc.8b04996 JUL 19 2018

Author(s)

 Zhang, Qian; Chen, Chen; Li, Nana; Huang, Quan; He, Yu; Liu, Xuqing; Wang, Bihan; Zhang, Dongzhou; Kim, Duck Young; Wang, Yonggang; Xu, Bo; Yang, Wenge

Corresponding author(s) 

 WANG Yonggang1; YANG Wenge1,6 
 yonggang.wang@hpstar.ac.cnyangwg@hpstar.ac.cn
 1.Ctr High Pressure Sci & Technol Adv Res HPSTAR, Shanghai 201203, Peoples R China.
 2. Carnegie Inst Sci, Geophys Lab, High Pressure Synerget Consortium HPSynC, Argonne, IL 60439 USA. 

Author(s) from IGCAS   HE Yu

View here for the details 

Copyright © Institute Of Geochemistry, Chinese Academy of Sciences All Rights Reserved.
Address: 99 West Lincheng Road, Guanshanhu District, Guiyang, Guizhou Province 550081, P.R.China
Tel: +86-851-85895239 Fax: +86-851-85895239 Email: web_en@mail.gyig.ac.cn