A typical mixed-land-use karst catchment in Guizhou Province, southwestern China, with well-developed conduit networks was studied to understand the spatiotemporal variability of nitrate sources and transformation processes. High nitrate concentrations were detected in the karstic study area, which is particularly vulnerable to anthropogenic pollution and is considered a representative catchment to understand the surface-underground system in southwestern China. The stable isotopes of water and nitrate (delta D-water, delta O-18(water), N-delta 15(nitrate), and delta O-18(nitrate)) were used to identify nitrate sources and to assess seasonal variations in hydrological processes affecting nitrate levels. Monthly sampling indicated that nitrate flux is strongly related to agricultural activities and the intensity of rainfall, which can accelerate transport between the surface water (SFW) and underground water (UGW) systems. Nitrate in water samples showed nitrification characteristics and was mainly derived from the oxidation of reductive fertilizers including organic N fertilizer. The isotopic composition of nitrate was affected by denitrification, particularly in the wet season. Isotopic signatures indicate that moderate evaporation occurs during the dry season. Denitrification in underground conduits appears to be relatively minor compared with that in SFW. The results of this study suggest that rainfall is an important factor influencing N flux, which has implications for water management. Publication name | VADOSE ZONE JOURNAL, 17 (1):10.2136/vzj2017.04.0071 MAY 17 2018 | Author(s) | Yue, Fu-Jun; Li, Si-Liang; Zhong, Jun; Liu, Jing | Corresponding author(s) | LI Siliang siliang.li@tju.edu.cn Tianjin Univ, Inst Surface Earth Syst Sci, Tianjin 300072, Peoples R China Tianjin Univ, State Key Lab Hydraul Engn Simulat & Safety, Tianjin 300072, Peoples R China | Author(s) from IGCAS | YUE Fujun; ZHONG Jun; LIU Jing | View here for the details
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