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A Brillouin scattering study of hydrous basaltic glasses: the effect of H2O on their elastic behavior and implications for the densities of basaltic melts TEXT SIZE: A A A
Hydrous basalt glasses with water contents of 0-6.82% were synthesized using a multi-anvil press at 1.0-2.0 GPa and 1200-1400 A degrees C. The starting materials were natural Mesozoic basalts from the eastern North China Craton (NCC). Their sound velocities and elastic properties were measured by Brillouin scattering spectroscopy. The longitudinal (V-P) and shear (V-S) wave velocities decreased with increasing water content. Increasing the synthesis pressure resulted in the glass becoming denser, and finally led to an increase in V-P. As the degree of depolymerization increased, the V-P, V (S), and shear and bulk moduli of the hydrous basalt glasses decreased, whereas the adiabatic compressibility increased. The partial molar volumes of water (v) under ambient conditions were independent of composition, having values of 11.6 +/- 0.8, 10.9 +/- 0.6 and 11.5 +/- 0.5 cm(3)/mol for the FX (Feixian), FW (Fuxin), and SHT (Sihetun) basalt glasses, respectively. However, the values measured at elevated temperatures and pressures are increasing with increasing temperature or decreasing pressure. The contrasting densities of these hydrous basalt melts with those previously reported for mid-ocean ridge basalt and preliminary reference Earth model data indicate that hydrous basalt melts may not maintain gravitational stability at the base of the upper mantle.
 

Publication name

 PHYSICS AND CHEMISTRY OF MINERALS, 44 (6):431-444; 10.1007/s00269-017-0870-9 JUN 2017

Author(s)

 Wu, Lei; Yang, De-Bin; Liu, Jun-Xiu; Hu, Bo; Xie, Hong-Sen; Li, Fang-Fei; Yu, Yang; Xu, Wen-Liang; Gao, Chun-Xiao

Corresponding author(s) 

 GAO Chunxiao 
 gaochunxiao2016@aliyun.com  
 Jilin Univ, Coll Earth Sci, State Key Lab Superhard Mat, Changchun 130012, Peoples R China. 

Author(s) from IGCAS   XIE Hongsen

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