We present a 3-year time series of lead (Pb) and mercury (Hg) concentrations and isotope signatures in total suspended particulate (TSP) matter, and as total gaseous Hg (TGM) in)(fan, Northwestern China. Mean concentrations of TSP (299 +/- 120 mu g m(-3)), Pb-TSP (0.33 +/- 0.15 mu g m(-3)) and: Hg-Tsp. (0.64 +/- 0.54 ng m(-3)), and TGM (5.7 +/- 2.7 ng m(-3)) were elevated. We find that atmospheric Pb levels in winter in Xi'an have decreased by 4.6% per year since 2003, yet remain elevated relative to air quality guidelines and therefore a major health concern. delta Hg-202(Tsp) and Delta Hg-199(Tsp) averaged -0.80 +/- 0.30 parts per thousand (1 sigma) and -0.02 +/- 0.10 parts per thousand (1 sigma) and delta Hg-202(TGM) and Delta Hg-199(TGM) averaged -0.08 +/- 0.41 parts per thousand (10) and 0.00 +/- 0.04 parts per thousand (1 sigma). Relative to raw coal from Shaanxi and surrounding provinces, delta Hg-202(TSP) is enriched in the light Hg isotopes, whereas delta Hg-202(TGM) is enriched in the heavy isotopes. TSP and TGM Delta Hg-199 signatures are indistinguishable from raw coal, indicating little photochemical mass independent fractionation of atmospheric Hg in the near-field urban-industrial environment. delta Hg-202(TGM) correlates significantly with TGM levels (r(2) = 0.3, p < 0.01) and likely reflects binary mixing of local industrial TGM emissions with global background TGM.