HAN Tao1,2, ZHU Xiaoqing1*, and LI Zengsheng1,2
(1 The State Key Laboratory of Ore Deposit Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550002, China
2 Graduate University of Chinese Academy of Sciences, Beijing 100049, China)
Abstract Adsorption experiments were made at room temperature and neutral pH value on different types of minerals associated with the Lower Cambrian black shale series polymetallic layers in Hunan and Guizhou provinces on nanometer-sized Pt colloids and PtCl42--bearing ionic solutions with an attempt to constrain the relationship between the different types of minerals in the polymetallic layers and the enrichment of platinum group elements (PGEs). Experimental results showed that the different types of minerals show strong selectivity to the adsorption of nanometer-sized Pt colloids and PtCl42--bearing ionic solutions. Metallic sulfides, organic matter and clay minerals are the strong adsorbents of PGEs, while quartz, albite, muscovite and other silicate minerals show a week adsorbility to both of them. This phenomenon is well consistent with the geological fact that metallic sulfides, organic matter and clay minerals in the polymetallic layers of the black shale series are the major carrier minerals of PGEs, giving a thorough explanation to the mechanism of enrichment of previous metal elements. Adsorption may be a principal mechanism of enrichment of precious metal elements under lower temperature conditions. The presence of the aforementioned strong adsorbents is the good geochemical barriers for the enrichment of PGEs.
Key words Hunan; Guizhou; Lower Cambrian; black shale; adsorption; precious metal; enrichment process
* Corresponding author, E-mail: zhuxqcas@sohu.com
CHINESE JOURNAL OF GEOCHEMISTRY Vol. 30, No. 3, 2011, page 375-381
© Science Press and Institute of Geochemistry, CAS and Springer-Verlag Berlin Heidelberg 2011
