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Evidence for an oxygen-depleted liquid outer core of the Earth TEXT SIZE: A A A

On the basis of geophysical observations, cosmochemical constraints, and high-pressure experimental data, the Earth's liquid outer core consists of mainly liquid iron alloyed with about ten per cent (by weight) of light elements(1,2). Although the concentrations of the light elements are small, they nevertheless affect the Earth's core: its rate of cooling, the growth of the inner core, the dynamics of core convection, and the evolution of the geodynamo(3,4). Several light elements-including sulphur, oxygen, silicon, carbon and hydrogen-have been suggested(2), but the precise identity of the light elements in the Earth's core is still unclear. Oxygen has been proposed as a major light element in the core on the basis of cosmochemical arguments and chemical reactions during accretion(5,6). Its presence in the core has direct implications for Earth accretion conditions of oxidation state, pressure and temperature. Here we report new shockwave data in the Fe-S-O system that are directly applicable to the outer core. The data include both density and sound velocity measurements, which we compare with the observed density and velocity profiles of the liquid outer core. The results show that we can rule out oxygen as a major light element in the liquid outer core because adding oxygen into liquid iron would not reproduce simultaneously the observed density and sound velocity profiles of the outer core. An oxygen-depleted core would imply a more reduced environment during early Earth

  Publication name  NATURE Volume: 479  Issue: 7374  Pages: 513-U236  Published: NOV 24 2011
  Author(s)

 Huang, Haijun; Fei, Yingwei; Cai, Lingcang; Jing, Fuqian; Hu, Xiaojun; Xie, Hongsen; Zhang, Lianmeng; Gong, Zizheng

  Corresponding author  

 FEI Yingwei
 fei@gl.ciw.edu
 Carnegie Inst Washington, Geophys Lab, 5251 Broad Branch Rd NW, Washington, DC 20015 USA

 Author(s) from IGCAS  XIE Hongsen

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